A study of electron scattering from benzene: excitation of the 1B1u, 3E2g, and 1E1u electronic states

dc.contributor.author Kato, H
dc.contributor.author Hoshino, M
dc.contributor.author Tanaka, Hiroshi
dc.contributor.author Limao-Vieira, Paulo
dc.contributor.author Ingolfsson, Oddur
dc.contributor.author Campbell, Laurence
dc.contributor.author Brunger, Michael James
dc.date.accessioned 2013-01-04T00:29:00Z
dc.date.available 2013-01-04T00:29:00Z
dc.date.issued 2011
dc.description.abstract We report results from measurements for differential and integral cross sections of the unresolved 1B1u and 3E2g electronic states and the 1E1u electronic state in benzene. The energy range of this work was 10–200 eV, while the angular range of the differential cross sections was -3°–130°. To the best of our knowledge there are no other corresponding theoretical or experimental data against which we can compare the present results. A generalized oscillator strength analysis was applied to our 100 and 200 eV differential cross section data, for both the 1B1u and 1E1u states, with optical oscillator strengths being derived in each case. The respective optical oscillator strengths were found to be consistent with many, but not all, of the earlier theoretical and experimental determinations. Finally, we present theoretical integral cross sections for both the 1B1u and 1E1u electronic states, as calculated within the BEf-scaling formalism, and compare them against relevant results from our measurements. From that comparison, an integral cross section for the optically forbidden 3E2g state is also derived. en
dc.identifier.citation Kato, H., Hoshino, M., Tanaka, H., Limao-Vieira, P., Ingolfsson, O., Campbell, L. and Brunger, M.J., 2011. A study of electron scattering from benzene: excitation of the 1B1u, 3E2g, and 1E1u electronic states. Journal of Chemical Physics, 134, 134308. en
dc.identifier.issn 0021-9606
dc.identifier.uri http://hdl.handle.net/2328/26545
dc.language.iso en
dc.oaire.license.condition.license In Copyright
dc.publisher American Institute of Physics en
dc.subject Physics en
dc.subject Electron impact excitation en
dc.subject Organic compounds en
dc.title A study of electron scattering from benzene: excitation of the 1B1u, 3E2g, and 1E1u electronic states en
dc.type Article en
local.contributor.authorOrcidLookup Brunger, Michael James: https://orcid.org/0000-0002-7743-2990 en_US
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